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Mechanism and kinetics of CO hydrogenation on metals

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Abstract

An antibatic relation has been established between the catalytic activities r of metals in relation to hydrogenation of CO and the selectivity in relation to methane\(S_{CH_4 } \). A mechanism is proposed for the reaction which makes it possible to interpret the observed kinetic relationships, the sequences of activities and selectivities, and also the relation between r and\(S_{CH_4 } \).

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev

    G. I. Golodets

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  1. G. I. Golodets
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 21, No. 5, pp. 549–553, September–October, 1985.

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Golodets, G.I. Mechanism and kinetics of CO hydrogenation on metals. Theor Exp Chem 21, 525–529 (1985). https://doi.org/10.1007/BF00944085

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  • DOI: https://doi.org/10.1007/BF00944085

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