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Mean bond energies and their application in the calculation of the heights of energy barriers of catalytic reactions

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The latest and most reliable data on heats of atomization were used for calculating the mean values of interatomic bond energies by the additive system. New or refined values were obtained in 22 cases.

  2. 2.

    A method was proposed for the approximate calculation of bond energies by solution of a system of equations, derived by the additive system for similar substances and containing the required values as unknowns.

  3. 3.

    Examples are given of the use of the bond energies found in the calculation of the height of energy barriers of reactions.

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Literature cited

  1. A. A. Balandin, Zhur. Obshch. Khim.12, 337 (1942); Zhur. Russ. Khim. Obshchest. 62, 703 (1930).

    Google Scholar 

  2. T. Cottrell, Strength of Chemical Bonds [Russian translation] (IL, Moscow, 1956).

    Google Scholar 

  3. V. N. Kondrat'ev. Usp. Khim.26, 861 (1957).

    Google Scholar 

  4. V. N. Tatevskii. Chemical Structure of Hydrocarbons [in Russian] (Izd. MGU, Moscow, 1953).

    Google Scholar 

  5. V. V. Korobov and A. V. Frost. Free Energies of Organic Compounds[in Russian] (Moscow, 1949); Collection: Physicochemical Properties, Edited by M. D, Tilicheev fin Russian] (Moscow-Leningrad, 1945) No. No. I-III, p. 51; F. Rossini, Select. Val. NBS, Circ. 500 (1952); F. Rossini et al., Select. Val. Phys. Therrnoch. Prop. (1953).

  6. G. Parks and L. Vaughan, J. Amer, Chem. Soc.73, 2380 (1951); A. A. Vvedenskii and A. V. Frost, Zhur. Obshchei Khim.2, 542 (1932).

    Google Scholar 

  7. A. V. Savitskii, Doklady Akad. Nauk SSSR87, 631 (1952).

    Google Scholar 

  8. K. Hartly, H. Pritchard and H. Skinner, Trans. Faraday Soc.47, 254 (1951).

    Google Scholar 

  9. A. Carson, E. Carson, and B. Wilmshurst, Nature170, 320 (1952).

    Google Scholar 

  10. A. A. Zil'berman-Granovskaya and E. A. Shugan, Zhur. Fiz. Khim.14, 1004 (1940).

    Google Scholar 

  11. C. Scheer, J. Chem. Phys.21, 1413 (1953).

    Google Scholar 

  12. S. Kaarsemaker and J. Coops, Recueil trav. chim.71, 261 (1952).

    Google Scholar 

  13. J. Knowlton and F. Rossini, J. Res. Nat. Bur. Standards43, 113 (1949).

    Google Scholar 

  14. A. A. Balandin and A. N. Ponomarev, Zhur. Obshchei Khim.26, 1146 (1956).

    Google Scholar 

  15. A. A. Balandin, N. V. Nikiforova, and L. Kh. Freidlin, Doklady Akad. Nauk SSSR112, 649 (1957).

    Google Scholar 

  16. A. A. Balandin and A. A. Tolstopyatova, Zhur. Fiz. Khim.30, 1367, 1636 (1956).

    Google Scholar 

  17. S. L. Kiperman and A. A. Balandin, Doklady Akad. Nauk SSSR113, 335 (1957); Zhur. Fiz. Khim.33, 828, 1045 (1959).

    Google Scholar 

  18. A. A. Balandin, G. I. Levi, and E. L. Broude, Izvest.Akad. Nauk SSSR Otdel. Khim. Nauk (1960) [in press].

  19. G. I. Levi and A. A. Balandin, Izvest. Akad. Nauk SSSR, Otdel Khim. Nauk, 1497(1958).

  20. A. A. Balandin and V. V. Patrikeev, Zhur. Obshch. Khim.11, 225 (1941).

    Google Scholar 

  21. A. A. Balandin, Uch. Zap. MGU175, 97 (1956).

    Google Scholar 

  22. J. Brihta and P. Luetic, Groat, chem. acta28, 93 (1956).

    Google Scholar 

  23. A. A. Balandin, O. K. Bogdanova, and A. P. Shcheglova, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk, 909 (1957); Izvest. Akad. Nauk SSSR, Otdel Khim. Nauk, (1960) [in press].

  24. A. A. Balandin, Doklady Akad. Nauk SSSR107, 85 (1956).

    Google Scholar 

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    G. I. Levi & A. A. Balandin

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  1. G. I. Levi
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  2. A. A. Balandin
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Levi, G.I., Balandin, A.A. Mean bond energies and their application in the calculation of the heights of energy barriers of catalytic reactions. Russ Chem Bull 9, 149–153 (1960). https://doi.org/10.1007/BF00942882

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  • DOI: https://doi.org/10.1007/BF00942882

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