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New spin-labeled biologically active compounds

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The paramagnetic derivatives of diethylenimino-S-triazine, pentaethyleniminocyclotriphospha-zatriene, and p-N-di-(β-chloroethyl)aminophenylacetic acid were synthesized.

  2. 2.

    The 4-aminomethyl- and 4-(β-aminoethyl)-2, 2, 6,6-tetramethylpiperidine-1-oxyls were synthesized.

  3. 3.

    A study was made of the reaction of the new spin-labeled compounds with DNA, synthetic polynucleotides, and albumin.

  4. 4.

    A study was made of the τsec of the spin-labeled polynucleotides as a function of the action of deoxyribonuclease, temperature, and the formation of purine-pyrimidine complexes.

  5. 5.

    The paramagnetic ethers of cellulose were obtained by the condensation of alkali cellulose with the paramagnetic derivatives of dichloro- and diethyleniminotriazine, and also of pentaethyleniminocyclo-triphosphazatriene.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    A. B. Shapiro, L. S. Bogach, V. M. Chumakov, A. A. Kropacheva, V. I. Suskina & É. G. Rozantsev

Authors
  1. A. B. Shapiro
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  2. L. S. Bogach
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  3. V. M. Chumakov
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  4. A. A. Kropacheva
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  5. V. I. Suskina
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  6. É. G. Rozantsev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2077–2082, September, 1975.

The authors express their gratitude to B. V. Rozynov for taking the mass spectra.

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Shapiro, A.B., Bogach, L.S., Chumakov, V.M. et al. New spin-labeled biologically active compounds. Russ Chem Bull 24, 1959–1964 (1975). https://doi.org/10.1007/BF00930174

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  • DOI: https://doi.org/10.1007/BF00930174

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