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1H and13C NMR spectra of certain bis-arene complexes of chromium and molybdenum

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The PMR and13C NMR spectra of a number of derivatives of dibenzenechromium, as well as bis-(ethylbenzene)molybdenum, were investigated.

  2. 2.

    In the case of coordination with a metal, the signals of the aromatic protons and carbon atoms of the benzene ring experience a substantial strong-field shift in comparison with the free arenes (by 2.5–3 ppm in the PMR spectra and by ∼50 ppm in the13C NMR spectra).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2006–2011, September, 1975.

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Nesmeyanov, A.N., Yur'eva, L.P., Kozyrkin, B.I. et al. 1H and13C NMR spectra of certain bis-arene complexes of chromium and molybdenum. Russ Chem Bull 24, 1887–1891 (1975). https://doi.org/10.1007/BF00930158

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  • DOI: https://doi.org/10.1007/BF00930158

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