Conclusions
-
1.
The PMR and13C NMR spectra of a number of derivatives of dibenzenechromium, as well as bis-(ethylbenzene)molybdenum, were investigated.
-
2.
In the case of coordination with a metal, the signals of the aromatic protons and carbon atoms of the benzene ring experience a substantial strong-field shift in comparison with the free arenes (by 2.5–3 ppm in the PMR spectra and by ∼50 ppm in the13C NMR spectra).
Similar content being viewed by others
Literature cited
C. Elschenbroich, J. Organometal. Chem.,14, 157 (1968).
A. N. Egorochkin, S. Ya. Khorshev, A. I. Burov, V. A. Umilin, and Yu. B. Zverev, Izv. Akad. Nauk SSSR, Ser. Khim., 2812 (1968).
J. W. Fitch, Dissert. Abstrs.,26, 190 (1965).
P. S. Skell, D. L. Williams-Smith, and M. J. McGlinchey, J. Amer. Chem. Soc.,95, 3337 (1973).
Ch. Elschenbroich, J. Organometal. Chem.,22, 677 (1970).
Ch. Elschenbroich and F. Stohler, J. Organometal. Chem.,67, C51 (1974).
E. O. Fischer and H. Brunner, Chem. Ber.,98, 175 (1965).
S. Ya. Khorshev, A. I. Burov, A. N. Egorochkin, V. A. Umilin, and I. N. Tyutyaev, Izv. Akad. Nauk SSSR, Ser. Khim., 111 (1973).
L. N. Mulay, E. G. Rochow, and E. O. Fischer, J. Inorgan. and Nucl. Chem.,4, 231 (1957).
S. E. Anderson, J. Organometal. Chem.,71, 263 (1974).
A. N. Nesmeyanov, L. P. Yur'eva, S. N. Levchenko, and N. N. Zaitseva, Izv. Akad. Nauk SSSR, Ser. Khim., 2865 (1974).
A. N. Nesmeyanov, L. P. Yur'eva, N. N. Zaitseva, E. I. Mysov, and A. M. Vainberg, Izv. Akad. Nauk SSSR, Ser. Khim., 165 (1973).
J. W. Emsley et al., High-Resolution NMR Spectroscopy, Pergamon.
H. Spiesecke and W. G. Schneider, J. Chem. Phys.,35, 731 (1961).
A. N. Nesmeyanov, É. I. Fedin, L. A. Fedorov, and P. V. Petrovskii, Zh. Strukt. Khim.,13, 1033 (1972).
P. C. Lauterbur, J. Amer. Chem. Soc.,83, 1838 (1961).
R. W. Crecely, K. M. Crecely, and J. H. Goldstein, Inorgan. Chem.,8, 252 (1969).
D. J. Thoennes, C. L. Wilkins, and W. S. Trahanovsky, J. Magn. Res.,13, 18 (1974).
G. L. Nelson, G. C. Levy, and J. D. Cargioli, J. Amer. Chem. Soc.,94, 3089 (1972).
A. N. Nesmeyanov, P. V. Petrovskii, L. A. Fedorov, V. I. Robas, and É. I. Fedin, Zh. Strukt. Khim.,14, 49 (1973).
A. A. Koridze, A. I. Mokhov, P. V. Petrovskii, and É. I. Fedin, Izv. Akad. Nauk SSSR, Ser. Khim., 2156 (1974).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2006–2011, September, 1975.
Rights and permissions
About this article
Cite this article
Nesmeyanov, A.N., Yur'eva, L.P., Kozyrkin, B.I. et al. 1H and13C NMR spectra of certain bis-arene complexes of chromium and molybdenum. Russ Chem Bull 24, 1887–1891 (1975). https://doi.org/10.1007/BF00930158
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00930158