Transesterification of ethyl acetate and butyl butyrate in the presence of sulfuric acid

  • N. S. Vedenyapina
  • V. V. Ivanov
  • N. S. Enikolopyan
Organic and Biological Chemistry
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Conclusions

The transesterification of ethyl acetate and butyl butyrate in the presence of sulfuric acid is zero order in ethyl acetate and first order in butyl butyrate. The activation energy of the reaction is 13 kcal /mole. The SNl mechanism was proposed.

Keywords

Acetate Ethyl Activation Energy Sulfuric Acid Ethyl Acetate 

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Literature cited

  1. 1.
    R. Breslau, Mechanism of Organic Reactions [Russian translation], Mir (1967).Google Scholar
  2. 2.
    V. V. Korshak and S. V. Vinogradova, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 334 (1951).Google Scholar
  3. 3.
    V. V. Korshak and S. V. Vinogradova, ibid., 179 (1950).Google Scholar
  4. 4.
    H. Becker, Introduction to Electron Theory of Organic Reactions [Russian translation], Mir (1965).Google Scholar
  5. 5.
    G. A. Olah, J. Am. Chem. Soc.,89, 5694 (1967).Google Scholar

Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • N. S. Vedenyapina
    • 1
  • V. V. Ivanov
    • 1
  • N. S. Enikolopyan
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR

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