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Influence of pressure and temperature on the direction of the diene condensation of trans-piperylene with methyl acrylate

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The influence of pressures up to 12,800 kg/cm2 and temperatures in the interval 60–140° on the isomeric composition of the adducts of diene condensation of trans-piperylene with methyl acrylate was investigated. The differences of the volumes, energies, and entropies of the corresponding transition states were calculated.

  2. 2.

    The transition state is evidently structurally closer to a plane-parallel model of the prereaction-complex than to the structure of the adduct.

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Literature cited

  1. B. S. Él'yanov, B. A. Rudenko, M. G. Gonikberg, and V. F. Kucherov, Izv. Akad. Nauk SSSR, Ser. Khim., 1082 (1964).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    S. K. Shakhova & B. S. Él'yanov

Authors
  1. S. K. Shakhova
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  2. B. S. Él'yanov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1504–1510, July, 1973.

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Shakhova, S.K., Él'yanov, B.S. Influence of pressure and temperature on the direction of the diene condensation of trans-piperylene with methyl acrylate. Russ Chem Bull 22, 1461–1465 (1973). https://doi.org/10.1007/BF00930038

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  • DOI: https://doi.org/10.1007/BF00930038

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