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Criteria of adiabativity in reactions of nucleophilic substitution in methyl halides

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The sufficient condition of adiabaticity of processes of nucleophilic substitution in methyl halides was obtained.

  2. 2.

    With the aid of this condition, one of the kinetic parameters of the reaction was estimated and is in agreement with the available experimental data.

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Literature cited

  1. R. R. Dogonadze and A. M. Kuznetsov, Results of Science, Electrochemistry. 1967 [in Russian], VINITI (1969).

  2. R. R. Dogonadze and A. M. Kuznetsov, Results of Science and Technology, Kinetics and Catalysis [in Russian], Vol. 2, VINITI (1973).

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  4. H. Fujimoto, S. Yamabe, and K. Fukui, Tetrahedron Letters, 439 (1971).

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Authors and Affiliations

  1. Institute of Electrochemistry, Academy of Sciences of the USSR, USSR

    E. D. German & A. M. Kuznetsov

Authors
  1. E. D. German
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  2. A. M. Kuznetsov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1473–1478, July, 1973.

The authors would like to express their deep gratitude to R. R. Dogonadze for his discussion of the work.

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German, E.D., Kuznetsov, A.M. Criteria of adiabativity in reactions of nucleophilic substitution in methyl halides. Russ Chem Bull 22, 1432–1435 (1973). https://doi.org/10.1007/BF00930032

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  • DOI: https://doi.org/10.1007/BF00930032

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