Skip to main content
Log in

Spreading of drops of polydimethylsiloxane on solid horizontal surfaces

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The conditions of spreading of drops of samples of polydimethylsiloxanes (PDMS) with a broad range of their viscosities were compared. It was found that on highly viscous compounds certain peculiarities, which are not characteristic of compounds with low viscosity, can be observed.

  2. 2.

    The influence of the volume of the drop on the rate of spreading is most pronounced for highly viscous PDMS. Increasing the volume of the drop decreases the rate of its spreading.

  3. 3.

    The deviation of the shape of the spreading drop from a spherical segment is manifested all the more, the higher the viscosity of the polymer, the larger the surface energy of the substrate, and the lower the volume of the drop.

  4. 4.

    An investigation of the spreading of drops in normal and inverted positions permits an evaluation of the influence of the mass of the drop on the rate of spreading.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. D. D. Eley, Adhesion, Oxford University Press, London (1961), p. 52.

    Google Scholar 

  2. K. Kapataru, Kolloid-Z.,192, 51 (1963).

    Google Scholar 

  3. H. Schonhorn, H. L. Frish, and T. K. Kwei, J. Appl. Phys.,37, 4967 (1966).

    Google Scholar 

  4. T. K. Kwei, H. Schonhorn, and H. L. Frisch, J. Coll. Interface Sci.,28, 543 (1968).

    Google Scholar 

  5. Ya. I. Frenkel', Fiz. Zh.,9, 385 (1945); Zh. Eksperim. i Teor. Fiz.,16, 29 (1946); C. Herring, J. Appl. Phys.,21, 301 (1950).

    Google Scholar 

  6. V. N. Tsvetkov and R. K. Chander, Vysokomolekul. Soed.,1, 607 (1959).

    Google Scholar 

  7. T. Takaoka and S. Ueda, J. Polymer Sci.,B4, 317 (1966).

    Google Scholar 

  8. V. Bazhant, V. Khvalovski, and I. Ratouski, Silicones [Russian translation], Khimizdat (1960), p. 253.

  9. D. G. Legrand and G. L. Gaines, Jr., J. Coll. Interface Sci.,31, 162 (1969).

    Google Scholar 

  10. R. J. Roe, J. Phys. Chem.,72, 2013 (1968).

    Google Scholar 

  11. H. W. Fox and W. A. Zisman, J. Colloid Sci.,5, 514 (1950).

    Google Scholar 

  12. Malcolm L. White, Clean Surfaces: Their Preparation and Characterization for Interfacial Studies, G. Goldfinger (editor), New York (1970).

  13. R. F. Willis and R. F. Shaw, J. Coll. Interface Sci.,31, 397 (1969).

    Google Scholar 

  14. H. Van Oene, J. E. Chang, and S. Newman, Adhesion,1, 54 (1969).

    Google Scholar 

  15. S. Strella, J. Appl. Phys.,41, 4242 (1970).

    Google Scholar 

  16. E. D. Shchukin, Yu. V. Goryunov, G. I. Den'shikova, N. V. Pertsev, and B. D. Summ, Kolloid-Z.,25, 108 (1963).

    Google Scholar 

  17. Yu. V. Naidich, Zh. Fiz. Khim.,42, 1946 (1968).

    Google Scholar 

  18. T. P. Yin, J. Phys. Chem.,73, 2413 (1969).

    Google Scholar 

  19. J. L. Moilliet, J. Coll. Interface Sci.,32, 165 (1970).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1467–1473, July, 1973.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ogarev, V.A., Ivanova, T.N., Arslanov, V.V. et al. Spreading of drops of polydimethylsiloxane on solid horizontal surfaces. Russ Chem Bull 22, 1426–1431 (1973). https://doi.org/10.1007/BF00930031

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00930031

Keywords

Navigation