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Electrolysis of aliphatic nitro compounds Communication 2. Electrochemical denitration of tetranitromethane and 1,1,1-trinitroethane

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    On the example of the electrolysis of tetranitromethane and 1,1,1-trinttroethatie, some rules for the electrochemical denitration of polynitroalkanes were discussed and it was shown that this method can be used for preparative purposes employing cathodes made from various materials.

  2. 2.

    It was proposed to use the electrochemical denitration method for the separation of mixtures of polynitroalkanes, and also for the removal of accompanying impurities from polynitroalkanes.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    V. A. Petrosyan, V. M. Khutoretskii, L. V. Okhlobystina & V. I. Slovetskii

Authors
  1. V. A. Petrosyan
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  2. V. M. Khutoretskii
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  3. L. V. Okhlobystina
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  4. V. I. Slovetskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2023–2027, September, 1973.

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Petrosyan, V.A., Khutoretskii, V.M., Okhlobystina, L.V. et al. Electrolysis of aliphatic nitro compounds Communication 2. Electrochemical denitration of tetranitromethane and 1,1,1-trinitroethane. Russ Chem Bull 22, 1972–1975 (1973). https://doi.org/10.1007/BF00929386

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  • DOI: https://doi.org/10.1007/BF00929386

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