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Study of rotations around C=C and C-N bonds in dienic δ- aminocarbonyl compounds by the NMR method

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

We determined the free activation energies of the rotations around the C =C and C -N bonds in some unsaturated aminocarbonyl compounds and studied their dependence on the substituents, number of double bonds, solvent, and the concentration. Explanations of the observed processes were proposed on the basis of the obtained data.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    E. P. Prokof'ev, Zh. A. Krasnaya & V. F. Kucherov

Authors
  1. E. P. Prokof'ev
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  2. Zh. A. Krasnaya
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  3. V. F. Kucherov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2013–2022, September, 1973.

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Prokof'ev, E.P., Krasnaya, Z.A. & Kucherov, V.F. Study of rotations around C=C and C-N bonds in dienic δ- aminocarbonyl compounds by the NMR method. Russ Chem Bull 22, 1963–1971 (1973). https://doi.org/10.1007/BF00929385

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  • DOI: https://doi.org/10.1007/BF00929385

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