Skip to main content
SpringerLink
Log in

Dielectrometric study of the interaction of silicon, germanium, and tin tetrachlorides with n-tributyl orthophosphate

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The systems SiCl4-TBP, GeCl4-TBP, and SnCl4-TBP in hexane (TBP is n-tributyl orthophosphate) were investigated by the method of dielectrometric titratton.

  2. 2.

    No appreciable interaction was detected in the systems SiCl4-TBP and GeCl4-TBP. Successive formation of molecular complexes with 1∶1 and 1∶2 compositions was found in the system SnCl4-TBP.

  3. 3.

    The equilibrium concentrations in reactions of complex formation of SnCl4 with TBP were calculated with an electronic computer, and the orders of the corresponding equilibrium constants were estimated.

  4. 4.

    The dipole moments of the complexes formed were determined, and hypotheses concerning their structure were advanced.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. E. N. Gur'yanova and I. P. Gol'dshtein, Zh. Obshch. Khim.,32, 12 (1962).

    Google Scholar 

  2. A. Weisberger, E. Proskauer, J. Riddik, and E. Toops, Organic Solvents [Russian translation], IL (1958), p. 276.

  3. I. P. Gol'dshtein, E. S. Shcherbakova, E. N. Gur'yanova, and L. A. Muzychenko, Teoret. i Eksperim. Khimiya,6, 634 (1970).

    Google Scholar 

  4. G. Roland, Spectrochim. Acta,25A, 1135 (1969).

    Google Scholar 

  5. O. A. Osipov and V. I. Minkin, Handbook of Dipole Moments [in Russian], Vysshaya Shkola (1965).

  6. Yu. Ya. Borovikov, E. V. Ryl'tsev, I. E. Boldeskul, N. G. Feshchenko, Yu. P. Makovetskii, and Yu. P. Egorov, Zh. Obshch. Khimii,40, 1957 (1970).

    Google Scholar 

  7. I. A. Shcheka, Zh. Obshch. Khimii,26, 1340 (1956).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. A. Baikov Institute of Metallurgy, Academy of Sciences of the USSR, USSR

    G. N. Kartsev, V. I. Aleinikov, N. V. Smirnova, Yu. M. Glubokov & É. S. Shcherbakova

  2. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, USSR

    G. N. Kartsev, V. I. Aleinikov, N. V. Smirnova, Yu. M. Glubokov & É. S. Shcherbakova

Authors
  1. G. N. Kartsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. I. Aleinikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. V. Smirnova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yu. M. Glubokov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. É. S. Shcherbakova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1972–1975, September, 1973.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kartsev, G.N., Aleinikov, V.I., Smirnova, N.V. et al. Dielectrometric study of the interaction of silicon, germanium, and tin tetrachlorides with n-tributyl orthophosphate. Russ Chem Bull 22, 1922–1924 (1973). https://doi.org/10.1007/BF00929376

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00929376

Keywords

Search

Navigation