Skip to main content
Log in

Potentiometric Determination of the Stability Constants of Nano-Silicon Complexes in Mixed Solvent at Different Temperatures

  • Original Paper
  • Published:
Silicon Aims and scope Submit manuscript

Abstract

The nano-silicon tetrachloride was prepared by an effective and environmentally friendly ball milling technique. The protonation constants of 2-oxo-N-(pyridine-2-yl)-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)acetamide (H2L) and the stability constants of its nano silicon complexes were estimated by the potentiometric technique at different temperatures 298, 308 & 318°K.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Muthuramalingam T, Mohan B, Vignesh S (2018) Performance analysis of pulse generators on residual stress of machined silicon steel using the EDM process. Silicon 10:1785–1792

    Article  CAS  Google Scholar 

  2. Yadav TP, Yadav RM, Singh DP (2012) Mechanical milling: a top down approach for the synthesis of nanomaterials and nanocomposites. Nanosci Nanotechnol 2:22–48

    Article  Google Scholar 

  3. Lin PC, Lin S, Wang PC, Sridhar R (2014) Techniques for physicochemical characterization of nanomaterials. Biotechnol Adv 32:711–726

    Article  Google Scholar 

  4. Franco JH, Silva BF, Oliveira RV, Meireles G, Oliveira DP, Castro AA, Ramalho TC, Zanoni MVB (2018) Biotransformation products of disperse dyes with rat liver microsomes by LC-MS/MS and theoretical studies with DNA: structure-mutagenicity relationship using Salmonella/microsome assay. Sci Total Environ 613:1093–1103

    Article  Google Scholar 

  5. Lino JBR, Rocha EP, Ramalho TC (2017) Value of NMR parameters and DFT calculations for quantum information processing utilizing phosphorus heterocycles. J Phys Chem 121:4486–4495

    Article  CAS  Google Scholar 

  6. Torres JA, Nogueira FGE, Silva MC, Lopes JH, Tavares TS, Ramalho TC, Corrêa AD (2017) Novel eco-friendly biocatalyst: soybean peroxidase immobilized onto activated carbon obtained from agricultural waste. RSC Adv 7:16460–16466

    Article  CAS  Google Scholar 

  7. Carlton CE, Ferreira PJ (2012) In situ TEM nanoindentation of nanoparticles. Micron 43:1134–1139

    Article  CAS  Google Scholar 

  8. Martins TLC, Ramalho TC, Figueroa-Villar JD, Flores AFC, Pereira CMP (2003) Theoretical and experimental 13C and 15N NMR investigation of guanylhydrazones in solution. Magn Reson Chem 41:983–988

    Article  CAS  Google Scholar 

  9. Silva TC, Almeida KJ, Pires MS, Castro AA, Gonçalves MA, Cunha EFF, Ramalho TC (2017) Theoretical structural and electronic analyses with emphasis on the reactivity of iron oxide prototypes in methane C–H bond activation. Reac Kinet Mech Cat 120:195–208

    Article  CAS  Google Scholar 

  10. Bjerrum J (1941) Metal ammine formation in aqueous solution, Haase P and Son, Copenhagen, Denmark

  11. Calvin M, Wilson KW (1945) Stability of chelate compounds. J Am Chem Soc 67:2003–2007

    Article  CAS  Google Scholar 

  12. Irving HM, Rossotti HS (1954) The calculation of formation curves of metal complexes from pH titration curves in mixed solvents. J Chem Soc:2904–2910

  13. Uitert LGV, Hass CG (1953) Studies on Coördination compounds. I. a method for determining thermodynamic equilibrium constants in mixed solvents. J Am Chem Soc 75:451–455

    Article  Google Scholar 

  14. Shukla JP, Tandon SG (1972) Corrections to pH measurements for titrations on dioxane–water mixtures. Electroanal Chem Interfacial Electrochem 35:423–427

    Article  CAS  Google Scholar 

  15. Harned HS, Owen BB (1967) The physical chemistry of electrolytic solution, 3rd. Reinhold, New York

    Google Scholar 

  16. Izatt RM, Hass CG, Block BP, Fernelius WC (1954) Studies on Coördination compounds. XII. Calculation of thermodynamic formation constants at varying ionic strengths. J Phys Chem 58:1133–1136

    Article  CAS  Google Scholar 

  17. Bell P, Rolin RO (1942) Studies in chemotherapy. VII. A theory of the relation of structure to activity of sulfanilamide type compounds. J Am Chem Soc 64:2905–2917

    Article  CAS  Google Scholar 

  18. Marshal PB (1995) Some chemical and physical properties association with histamine antagonism. Br J Pharmacol 10:270–278

    Google Scholar 

  19. Martin A, Bustamanate P, Chum AHC (1993) Physical pharmacy, 4th. ed. Lea & Febiger, Philadelphia

    Google Scholar 

  20. Myer MC, Guttman DE (1968) Interactions of xanthine derivatives with bovine serum albumin. 3 Inhibition of binding J Pharm Sci 57:245–249

    Google Scholar 

  21. Brodie BB (1964) Physico-chemical factors in drug absorption. In: Binns TB (ed) Absorption and distribution of drugs. Williams & Wilikins, Baltimore, pp 16–48

    Google Scholar 

  22. Abd El-Wahed MG, Metwally SM, El-Gamel MM, Abd-el Haleem SM (2001) Thermodynamic and electrical properties of aminophenol and Anthranilic acid complexes with some transition metals. Bull Kor Chem Soc 22:663–668

    Google Scholar 

  23. Moeller T, Martin DF, Thompson LC, Ferrus R, Feistel GR, Randal WJ (1965) The coordination chemistry of yttrium and the rare earth metal ions. Chem Rev 65:1–50

    Article  CAS  Google Scholar 

  24. Snavely FA, Krecker BD (1959) Metal derivatives of aryl azo Pyrazolone Dyes. III. Molarity quotients of Para-and meta-substituted Pyrazolone dyes. J Am Chem Soc 81:4199–4200

    Article  CAS  Google Scholar 

  25. Gutmann K (1966) Conductimetric titration of charge transfer complexes in solution. Electrochim Acta 11:555–568

    Article  CAS  Google Scholar 

  26. Singh P, Ojha AC (1980) Synthesis of N-isonicotinyl-3-methyl-4-(substituted hydrazono)-2-pyrazolin-5-one. J Indian Chem Soc 57:1172–1173

    CAS  Google Scholar 

  27. Abdel-latif SA, Mansour SE, Fatouh AA (2010) Potentiometric, spectrophotometric, conductimetric and thermodynamic studies on some transition metal complexes derived from 3-methyl-1-phenyl- and1, 3-diphenyl-4-arylazo-5-pyrazolones. Nat Sci 2:793–802

    CAS  Google Scholar 

  28. Haschke JM, Hodges AE, Smith CM, Oetting FL (1980) Equilibria and thermodynamic properties of the plutonium-hydrogen system. J Less Common Met 73:41–48

    Article  CAS  Google Scholar 

  29. William WP (1993) Inorganic chemistry, 2nd ed. Academic Press Inc, Cambridge

  30. Mcaulery A, Nacollas GH (1961) Thermodynamics of ion association. Part V1I.l A % x m transition-metal oxalates. J Chem Soc:2215–2221

  31. Abd El-Rhim AH (1999) In Faculty of Science. Mansoura University, Egypt

    Google Scholar 

  32. Sari H, Can M, Macit M (2005) Scientific paper potentiometric and theoretical studies of stability constants of glyoxime derivatives and their nickel, copper, cobalt and zinc complexes. Acta Chim Slov 52:317–322

    CAS  Google Scholar 

  33. Shokrollahi A, Ghaedi M, Ghaedi H (2007) Potentiometric and spectrophotometric studies of copper(II) complexes of some ligands in aqueous and nonaqueous solution. J Chin Chem Soc 54:933–940

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Rania R. Zaky.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zaky, R.R., Al-Ahmed, Z.A. Potentiometric Determination of the Stability Constants of Nano-Silicon Complexes in Mixed Solvent at Different Temperatures. Silicon 11, 2811–2818 (2019). https://doi.org/10.1007/s12633-019-0075-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12633-019-0075-6

Keywords

Navigation