Skip to main content
SpringerLink
Log in

Synthesis and chemical properties of some carboranylmethylphosphinite esters

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have prepared O-etbyl carboranylmethylphosphinites and studied their reactions with p-nitrophenyl azide, chlorine, dimethyl sulfate, methyl iodide, chloral, and water. The carboranylmethylphosphinites exhibit greater reactivity than carboranylphosphonites.

  2. 2.

    The carboranyl group attached to the phosphorus atom has a pronounced electron-acceptor effect, and substituents attached to the second carbon atom of the o-carboranyl nucleus have a weak influence on the overall electronic effect ofthe carboranyl group.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. N. N. Godovikov, A. N. Degtyarev, V. I. Bregadze, and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim., 2568 (1975).

  2. E. Steininger, Chem. Ber.,95, 2993 (1962).

    Google Scholar 

  3. N. N. Godovikov, A. N. Degtyarev, V. I. Bregadze, and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim., 2797 (1975).

  4. E. I. Matrosov, A. G. Kozachenko, and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim., 1476 (1976).

  5. I. N. Zhmurova, V. G. Yurchenko, V. P. Kukhar', and A. A. Zolotareva, Zh. Obshch. Khim.,42, 6256 (1972).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. N. Degtyarev, N. N. Godovikov, V. I. Bregadze, E. I. Matrosov, T. M. Shcherbina & M. I. Kabachnik

Authors
  1. A. N. Degtyarev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. N. Godovikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. I. Bregadze
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. I. Matrosov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. T. M. Shcherbina
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. M. I. Kabachnik
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2099–2104, September, 1978.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Degtyarev, A.N., Godovikov, N.N., Bregadze, V.I. et al. Synthesis and chemical properties of some carboranylmethylphosphinite esters. Russ Chem Bull 27, 1851–1857 (1978). https://doi.org/10.1007/BF00929237

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00929237

Keywords

Search

Navigation