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Carboxylation of dialkylaluminum halides

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Alkylaluminum halides of the types R2A1C1, RAlCl2, and R2AlBr react with CO2 to form carboxylic acids.

  2. 2.

    The kinetics of the carboxylation of higher R2AlCl with different alkyl chain lengths have been studied at 110–146°C.

  3. 3.

    The possibility of jointly preparing carboxylic acids and aliphatic alcohols from R2AlCl with quantitative utilization of both Al-C bonds has been demonstrated.

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Literature cited

  1. L. I. Zakharkin and V. V. Gavrilenko, Dokl. Akad. Nauk SSSR,118, 713 (1958).

    Google Scholar 

  2. K. Ziegler, F. Krupp, K. Weyer, and W. Larbig, Liebigs Ann. Chem.,629, 251 (1960).

    Google Scholar 

  3. V. P. Yur'ev, A. V. Kuchin, and G. A. Tolstikov, Izv. Akad. Nauk SSSR, Ser. Khim., 853 (1974).

  4. J. Weidlein, Z. Anorg. Allg. Chem.,378, 245 (1970).

    Google Scholar 

  5. J. Weidlein, J. Organometall. Chem.,49, 257 (1973).

    Google Scholar 

  6. V. Grignard and R. Jenkins, C. R. Acad. Sci.,179, 89 (1924).

    Google Scholar 

  7. Belgian Patent 553, 721 (1956); Ref. Zh. Khim., ZL300 (1962).

  8. L. I. Zakharkin, V. V. Gavrilenko, and V. G. Golubev, Izv, Akad. Nauk SSSR, Ser. Khim., 1564 (1971).

  9. V. K. Golubev, V. M. Smagin, V. V. Gavrilenko, and L. I. Zakharkin, Zh. Obshch. Khim.,45, 1301 (1975).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. M. Smagin, V. V. Gavrilenko, L. I. Zakharkin & V. K. Golubev

  2. All-Union Scientific-Research Institute of Organic Synthesis, USSR

    V. M. Smagin, V. V. Gavrilenko, L. I. Zakharkin & V. K. Golubev

Authors
  1. V. M. Smagin
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  2. V. V. Gavrilenko
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  3. L. I. Zakharkin
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  4. V. K. Golubev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2094–2098, September, 1978.

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Smagin, V.M., Gavrilenko, V.V., Zakharkin, L.I. et al. Carboxylation of dialkylaluminum halides. Russ Chem Bull 27, 1847–1851 (1978). https://doi.org/10.1007/BF00929236

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  • DOI: https://doi.org/10.1007/BF00929236

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