Conclusions
-
1.
A study has been made of the ESR spectra of radicals formed in the reaction of the orthoquinones with group VA elements. It has been shown that these radicals contain the group VA element in valence states three and five.
-
2.
Discussion is given of the differences of the ESR spectra of radicals containing these elements in the trivalent and pentavalent states.
Similar content being viewed by others
Literature cited
A. I. Prokof'ev, A. A. Khodak, N. A. Malysheva, N. N. Bubnov, S. P. Solodovnikov, I. S. Belostotskaya, V. V. Ershov, and M. I. Kabachnik, Dokl. Akad. Nauk SSSR,240, 358 (1978).
A. I. Prokof'ev, N. A. Malysheva, N. N. Bubnov, S. P. Solodovnikov, and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim.,1978, 1969.
A. I. Prokof'ev, N. N. Bubnov, S. P. Solodovnikov, and M. I. Kabachnik, Tetrahedron, Lett.,1973, 2479.
K. U. Ingold and B. P. Roberts, Free Radical Substitution Reactions, Wiley (1971).
G. A. Abakumov and E. S. Klimov, Zh. Strukt. Khim.,13, 922 (1972).
J. E. Wertz and J. R. Bolton, Electron Spin Resonance, Theory and Practical Applications, McGraw-Hill (1972).
A. I. Prokof'ev, N. A. Malysheva, N. N. Bubnov, S. P. Solodovnikov, I. S. Belostotskaya, N. L. Komissarova, V. V. Ershov, and M. I. Kabachnik, Dokl. Akad. Nauk SSSR,229, 1396 (1976).
A. I. Prokof'ev, A. A. Khodak, N. A. Malysheva, P. V. Petrovskii, N. N. Bubnov, S. P. Solodovnikov, and M. I. Kabachnik, Dokl. Akad. Nauk SSSR,240, 92 (1978).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1976–1981, September, 1978.
Rights and permissions
About this article
Cite this article
Prokof'ev, A.I., Malysheva, N.A., Tumanskii, B.L. et al. The reactions of group VA elements with orthoquinones. Russ Chem Bull 27, 1738–1743 (1978). https://doi.org/10.1007/BF00929214
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00929214