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Stability of tetraoxides of chemical elements

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Abstract

Published data on the synthesis of eight-valence iridium and some other elements, and also works casting doubt on the fact of preparing iron and some 5f-elements in the oxidation state +8 were analyzed. Supposed methods (nuclear-chemical and pulse radiolysis methods) for Pu(VIII) and Am(VIII) detection and the method of matrix isolation at a temperature of 4–6 K for stabilization of eight-valence in Fe, Pu, and Am were considered.

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Authors and Affiliations

  1. A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31/4, Moscow, 119071, Russia

    V. P. Shilov, A. M. Fedoseev & A. V. Gogolev

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  1. V. P. Shilov
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  2. A. M. Fedoseev
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  3. A. V. Gogolev
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Correspondence to V. P. Shilov.

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Original Russian Text © V.P. Shilov, A.M. Fedoseev, A.V. Gogolev, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 10, pp. 1605–1608.

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Shilov, V.P., Fedoseev, A.M. & Gogolev, A.V. Stability of tetraoxides of chemical elements. Russ J Gen Chem 87, 2265–2268 (2017). https://doi.org/10.1134/S1070363217100036

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  • DOI: https://doi.org/10.1134/S1070363217100036

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