Conclusions
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1.
A study has been made of the effect of concentration and temperature on the rate of exchange in the (CH3)3SnCl+(CH3)3SnSC6H5 system in toluene. The reaction rate has been found to vary inversely with the temperature.
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2.
It is suggested that exchange between trimethyltin chloride and thiophenylate in inert medium proceeds through the formation of six- and eight-membered cyclic transition states with delocalized bonds.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1526–1530, July, 1977.
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Korniets, E.D., Fedorov, L.A., Fedin, É.I. et al. A PMR study of exchange between trimethyltin chloride and thiophenolate. Russ Chem Bull 26, 1401–1405 (1977). https://doi.org/10.1007/BF00928514
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DOI: https://doi.org/10.1007/BF00928514