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Perchloric acid in the synthesis of covalent perchlorates

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The authors have investigated the conditions of hydration of multivalent metal ions by perchloric acid; hydration does not occur in acid containing oxonium perchlorate. Transfer of water from perchloric acid to the ion being hydrated proceeds via a stage of formation of oxonium perchlorate by equilibrial auto-dehydration.

  2. 2.

    A procedure has been developed for obtaining anhydrous perchlorates and perchlorato complexes in liquid perchloric acid.

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Authors and Affiliations

  1. Institute of New Chemical Problems, Academy of Sciences of the USSR, Chernogolovka

    Z. K. Nikitina & V. Ya. Rosolovskii

Authors
  1. Z. K. Nikitina
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  2. V. Ya. Rosolovskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1466–1469, July, 1977.

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Nikitina, Z.K., Rosolovskii, V.Y. Perchloric acid in the synthesis of covalent perchlorates. Russ Chem Bull 26, 1348–1351 (1977). https://doi.org/10.1007/BF00928501

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  • DOI: https://doi.org/10.1007/BF00928501

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