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Catalytic performance on the water decontamination and the water-splitting electrolysis of new phosphite salts (enH2)[M(H2O)6](HPO3)2 (M=Co, Ni and Mg)

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Abstract

Three new organic–inorganic hybrid phosphites salts, namely, (enH2)[M(H2O)6](HPO3)2, with [M = Co (1), Ni (2) and Mg (3), and “en” refers to ethylenediamine C2N2H8] have been synthesized at room temperature by the slow evaporation method. The solid-state structures were solved from single crystal X-ray diffraction data. These compounds are isostructural, all crystallizing in the orthorhombic system, space group, Pbca (no 61). The FTIR spectroscopy shows the expected bands of ethylenediamine (en), water molecules, and hydrogen-phosphite oxoanion groups. The thermal stability until 100 °C of the three compounds was confirmed using combined analyses (TGA/DTA, powder X-ray diffraction and Raman spectroscopy). Two catalytic activity performances were investigated: the catalytic efficiency on the water decontamination of the three compounds by the reduction of three nitrophenol isomers and the Hydrogen Evolution Reaction (HER) in an alkaline environment. The three hybrid compounds turned out to be very efficient new catalysts for reducing the three nitrophenol isomers. The fastest electron transport and the most favorable HER reaction kinetics are displayed by (enH2)[Ni(H2O)6](HPO3)2, while the highest current density with the lowest overpotential was obtained for (enH2)[Co(H2O)6](HPO3)2.

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Funding

ZE thanks the Scientific and Technological Research Council of Turkey (Grant Number: TUBITAK 2219) for a postdoctoral fellowship. MDS thanks the Royal Society for a University Research Fellowship (150104). This research was supported by the project 20-LM2023051 of the Czech Science Foundation.

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Authors and Affiliations

  1. Engineering Laboratory of Organometallic, Molecular Materials, and Environment (LIMOME), Faculty of Sciences, University Sidi Mohamed Ben Abdellah, 30000, Fez, Morocco

    Mohamed Akouibaa, Rachid Ouarsal & Mohammed Lachkar

  2. Marrakech, Morocco

    Brahim El Bali

  3. Institute of Physics of the Czech Academy of Sciences, Na Slovance 2, 182 21, Prague 8, Czech Republic

    Morgane Poupon, Joris More-chevalier, Jan Pokorny, Václav Eigner & Michal Dusek

  4. WestCHEM, School of Chemistry, University of Glasgow, Glasgow, G12 8QQ, UK

    Mark D. Symes & Zeliha Ertekin

  5. Department of Chemistry, Faculty of Science, Hacettepe University, Beytepe, 06800, Ankara, Turkey

    Zeliha Ertekin

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  1. Mohamed Akouibaa
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Contributions

MA performed all the syntheses and descibed the results, helped somewhere by RO under the supervision of ML; MP, VE and MD performed the single crystal X-ray diffraction, JM and JP measured the Raman spectra and TG/TDA measurements, ZE and MDS studied the catalytic performance of the searched materials. BEB suggested the research and validated the manuscript.

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Correspondence to Brahim El Bali.

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Akouibaa, M., El Bali, B., Poupon, M. et al. Catalytic performance on the water decontamination and the water-splitting electrolysis of new phosphite salts (enH2)[M(H2O)6](HPO3)2 (M=Co, Ni and Mg). J Appl Electrochem (2024). https://doi.org/10.1007/s10800-024-02097-w

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