Skip to main content
SpringerLink
Log in

Solubility of titanium ethylate in ethyl alcohol

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The authors have studied solubility in the Ti(OEt)4-EtOH system between −150 and 38°C. Unsolvated Ti(OEt)4 crystallizes from solution at temperatures from the melting point to−13°C. At lower temperatures the crystals are of a solvate, probably with 1∶1 composition.

  2. 2.

    The metastable states characteristic of the system are evidently due to molecular polymorphism of Ti(OEt)4, which exists as various types of associates both in solution and in the solid state.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. L. Suvorov and S. S. Spasskii, Usp. Khim.,28, 1267 (1959).

    Google Scholar 

  2. R. Feld and P. L. Cowe, The Organic Chemistry of Titanium, Plenum Pub. (1965).

  3. J. A. Ibers, Nature,197, 686 (1963).

    Google Scholar 

  4. D. C. Bradley, Adv. Inorg. Radiochem.,15, 259 (1972).

    Google Scholar 

  5. W. R. Russo and W. H. Nelson, J. Am. Chem. Soc.,92, 1521 (1970).

    Google Scholar 

  6. D. C. Bradley and C. E. Holloway, Inorg. Chem., 1163 (1964).

  7. D. C. Bradley and M. I. Hiller, Trans. Faraday Soc.,62, 2367 (1966).

    Google Scholar 

  8. E. K. Piiroya, Tr. Tallin. Politekh. Inst., Ser. A,285, 65 (1970).

    Google Scholar 

  9. H. Kriegsmann and K. Licht, Z. Elektrochem.,62, 1163 (1958).

    Google Scholar 

  10. C. G. Barraclough, D. C. Bradley, J. Lewis, and I. M. Thomas, J. Chem. Soc., 2601 (1961).

  11. G. A. Kakos and G. Winter, Aust. J. Chem.,21, 793 (1968).

    Google Scholar 

  12. G. Charlot, Methods of Analytical Chemistry: Quantitative Analysis of Inorganic Compounds [Russian translation from French original], Khimiya (1969), p. 1032.

Download references

Author information

Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    E. P. Turevskaya & N. Ya. Turova

Authors
  1. E. P. Turevskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. Ya. Turova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1463–1466, July, 1977.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Turevskaya, E.P., Turova, N.Y. Solubility of titanium ethylate in ethyl alcohol. Russ Chem Bull 26, 1345–1348 (1977). https://doi.org/10.1007/BF00928500

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00928500

Keywords

Search

Navigation