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Investigation of the dipole-dipole interaction of phosphoryl compounds with the medium by the method of ir spectroscopy

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The Interaction of organophosphorus esters, amides, acid chlorides, and trialkyl(aryl)phosphine oxides, possessing a phosphoryl group, with the medium occurs according to the same mechanism, as is indicated by the linearity of the change in the frequency of the valence vibrations of the P=O bonds under the influence of the medium.

  2. 2.

    The interaction of phosphoryl compounds with the medium is intensified as their dipole moments increase, which may be due to the increase in polarity of the P=O bond.

  3. 3.

    The ability of phosphoryl compounds to interact with the medium depends on the intermolecular effects of the substituents at the phosphorus, determined by the Taft induction constants.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Branch of the Academy of Sciences of the USSR, USSR

    R. R. Shagidullin, V. E. Bel'skii, L. Kh. Ashrafullina, L. A. Kudryavtseva & B. E. Ivanov

Authors
  1. R. R. Shagidullin
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  2. V. E. Bel'skii
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  3. L. Kh. Ashrafullina
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  4. L. A. Kudryavtseva
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  5. B. E. Ivanov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2502–2504, November, 1973.

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Shagidullin, R.R., Bel'skii, V.E., Ashrafullina, L.K. et al. Investigation of the dipole-dipole interaction of phosphoryl compounds with the medium by the method of ir spectroscopy. Russ Chem Bull 22, 2442–2444 (1973). https://doi.org/10.1007/BF00926390

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  • DOI: https://doi.org/10.1007/BF00926390

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