Conclusions
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1.
α-Chloromethylalkyl sulfides exist in solutions in a gauche-conformation.
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2.
The C-O and C-S bonds have axially nonsymmetrical ellipsoids of polarizability.
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3.
In α-chloroethers, the anisotropy of the polarizability of the C-C bond is lowered as a result of interaction with the oxygen atom.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2413–2416, November, 1973.
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Arbuzov, B.A., Lapkin, I.I., Saitkulova, F.G. et al. Dipole moments and molar Kerr constants of certain chloromethylalkyl sulfides. Russ Chem Bull 22, 2359–2362 (1973). https://doi.org/10.1007/BF00926371
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DOI: https://doi.org/10.1007/BF00926371