Skip to main content
SpringerLink
Log in

Esters of trivalent phosphorus thioacids

Communication 15. Reaction of esters of thiophosphonous chlorides and thiophosphorous dichlorides with propargyl alcohol and propargyl mercaptan

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of S-alkyl alkyl(aryl)chlorothiophosphonites with propargyl alcohol or with propargyl mercaptan in the presence of a base leads to the formation of S-alkyl alkyl(aryl)allenylthio(dithio)phosphinates, which when heated with a sodium alcoholate are converted to S-alkyl alkyl(aryl)-1-propynylthiophosphinates.

  2. 2.

    Alkyl(aryl)dichlorothiophosphites react with propargyl alcohol to give S-alkyl(aryl)allenylchlorothiophosphonates, while the reaction of ethyldichlorophosphine with propargyl mercaptan leads to the formation of ethylallenylchlorothionophosphine.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. N. I. Rizpolozhenskii, V. D. Akamsin, and R. M. Eliseenkova, Izv. Akad. Nauk SSSR, Ser. Khim.,1973, 85.

  2. A. N. Pudovik and I. M. Aladzheva, Zh. Obshch. Khim.,33, 707 (1963).

    Google Scholar 

  3. A. N. Pudovik, I. M. Aladzheva, and L. N. Yakovenko, Zh. Obshch. Khim.,35, 1210 (1965).

    Google Scholar 

  4. V. N. Pastushkov, Yu. A. Kondrat'ev, S. Z. Ivin, and Yu. K. Knobel', Zh. Obshch. Khim.,35, 672 (1968).

    Google Scholar 

  5. S. Z. Ivin, V. N. Pastushkov, Yu. A. Kondrat'ev, Yu. F. Ogloblin, and V. V. Tarasov, Zh. Obshch. Khim.,38, 2069 (1968).

    Google Scholar 

  6. Yu. A. Kondrat'ev, V. V. Tarasov, N. M. Ivakina, S. Z. Ivin, and V. N. Pastushkov, Zh. Obshch. Khim.,39, 2590 (1968).

    Google Scholar 

  7. L. J. Bellamy, Infrared Spectra of Complex Molecules [Russian translation], IL (1963), p. 89.

  8. V. N. Pastushkov, Yu. A. Kondrat'ev, S. Z. Ivin, E. S. Vdovina, and A. S. Vasil'ev, Zh. Obshch. Khim.,38, 1407 (1968).

    Google Scholar 

  9. A. N. Pudovik and N. G. Khusainova, Zh. Obshch. Khim.,39, 1417 (1969).

    Google Scholar 

  10. V. Mark, C. H. Dungan, M. M. Grutchfield, and J. R. Van Wazer, Topics in Phosphorus Chemistry,5, 361 (1967).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    R. M. Eliseenkova, N. I. Rizpolozhenskii & V. D. Akamsin

Authors
  1. R. M. Eliseenkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. I. Rizpolozhenskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. D. Akamsin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2755–2758, December, 1973.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Eliseenkova, R.M., Rizpolozhenskii, N.I. & Akamsin, V.D. Esters of trivalent phosphorus thioacids. Russ Chem Bull 22, 2687–2690 (1973). https://doi.org/10.1007/BF00926138

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00926138

Keywords

Search

Navigation