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Carbonylation reactions

Communication 14. Intermediate formation of charge-transfer complexes in carbonylation of amines with carbon monoxide initiated by copper(II) salts

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

From the UV spectra it follows that the chain reaction for the carbonylation of piperidine, initiated by CuCl2, proceeds via the Intermediate formation of charge-transfer complexes, in which the Cu2+ ion undergoes oxidation-reduction reaction with the free electron pair of the amine.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    B. K. Nefedov, V. A. Petukhov & Ya. T. Éidus

Authors
  1. B. K. Nefedov
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  2. V. A. Petukhov
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  3. Ya. T. Éidus
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2705–2708, December, 1973.

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Nefedov, B.K., Petukhov, V.A. & Éidus, Y.T. Carbonylation reactions. Russ Chem Bull 22, 2640–2642 (1973). https://doi.org/10.1007/BF00926127

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  • DOI: https://doi.org/10.1007/BF00926127

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