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Mycobacterium polysaccharides. 1. 4-O-[(S)-1′-Carboxyethyl]-D-mannose isolated from the extracellular polysaccharide of mycobacterium lacticolum strain 121

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A new acid monosaccharide, viz., 4-0-[(S)-1′-carboxyethyl]-D-mannose, has been isolated from the extracellular polysaccharide produced by M. lacticolum, and its structure demonstrated by back-synthesis and by comparison of its13C NMR spectrum with those of authentic samples in which the lactic acid residue has an (S) and (R) configuration.

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Literature cited

  1. N. K. Kochetkov, B. A. Dmitriev, L. V. Bakinovskii, and V. L. L'vov, Bioorg. Khim.,1, 1237 (1975).

    Google Scholar 

  2. N. K. Kochetkov, B. A. Dmitriev, and L. V. Bakinovskii (Backinowsky), Carbohyd. Res.,51, 229 (1976).

    Google Scholar 

  3. N. K. Kochetkov, B. A. Dmitriev, and V. L. L'vov, Carbohyd. Res.,54, 253 (1976).

    Google Scholar 

  4. L. Kenne, B. Lindberg, B. Lindqvist, J. Lönngren, B. Arie, R. G. Brown, and J. E. Stewart, Carbohyd. Res.,51, 287 (1976).

    Google Scholar 

  5. B. Lindberg, B. Lindqvist, J. Lönngren, and W. Nimmich, Carbohyd. Res.,49, 411 (1976).

    Google Scholar 

  6. N. K. Kochetkov, O. S. Chizhov, A. F. Sviridov, and Kh. A. Arifkhodzhaev, Bioorg. Khim.,2, 1140 (1976).

    Google Scholar 

  7. E. S. Wallis and J. F. Len, in: Organic Reactions, Vol. 3, John Wiley, New York.

  8. V. Smirnyagin, and C. T. Bishop, Can. J. Chem.,46, 3085 (1968).

    Google Scholar 

  9. T. Trnka and M. Cerný, Coll. Czech. Chem. Commun.,36, 2216 (1971).

    Google Scholar 

  10. G. O. Aspinall and G. Zweifel, J. Chem. Soc., 2271 (1957).

  11. J. Fu Shou-Cheng, S. M. Birnbaum, and J. P. Greenstein, J. Am. Chem. Soc.,76, 6065 (1954).

    Google Scholar 

  12. P. SinaŸ, M. D. A. Halford, M. S. Choudhary, P. H. Gross, and R. W. Jeanloz, J. Biol. Chem.,247, 391 (1972).

    PubMed  Google Scholar 

  13. P. A. J. Gorin, Can. J. Chem.,52, 458 (1974); Carbohyd. Res.,39, 3 (1975).

    Google Scholar 

  14. G. Zemplen and E. Pascu, Chem. Ber.,62, 1613 (1929).

    Google Scholar 

  15. S. Hakomori, J. Biochem.,55, 205 (1964).

    PubMed  Google Scholar 

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See [6] for preliminary communication.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 438–442, February, 1979.

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Arifkhodzhaev, K.A., Sviridov, A.F., Shashkov, A.S. et al. Mycobacterium polysaccharides. 1. 4-O-[(S)-1′-Carboxyethyl]-D-mannose isolated from the extracellular polysaccharide of mycobacterium lacticolum strain 121. Russ Chem Bull 28, 405–409 (1979). https://doi.org/10.1007/BF00925896

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  • DOI: https://doi.org/10.1007/BF00925896

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