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The interaction of 3-hydroxyphenoxyl and 5-methyl-3-hydroxyphenoxyl radicals with copper(II) ions

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Absorption spectra have been obtained for 3-hydroxyphenoxyl and 5-methyl-3-hydroxyphenoxyl radicals. Rate constants for the recombination of these radicals have also been obtained.

  2. 2.

    These radicals are oxidized by Cu2+ ions. Absorption spectra have been obtained for the intermediate complex, and rate constants for the electron-transfer reaction calculated.

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Author information

Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    I. V. Renge, I. V. Khudyakov & M. Ya. Gubergrits

  2. Institute of Chemistry, Academy of Sciences of the ESSR, Tallin

    I. V. Renge, I. V. Khudyakov & M. Ya. Gubergrits

Authors
  1. I. V. Renge
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  2. I. V. Khudyakov
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  3. M. Ya. Gubergrits
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 304–307, February, 1979.

The authors would like to thank V. A. Kuz'min for his aid in this work.

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Renge, I.V., Khudyakov, I.V. & Gubergrits, M.Y. The interaction of 3-hydroxyphenoxyl and 5-methyl-3-hydroxyphenoxyl radicals with copper(II) ions. Russ Chem Bull 28, 278–281 (1979). https://doi.org/10.1007/BF00925866

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  • DOI: https://doi.org/10.1007/BF00925866

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