Conclusions
-
1.
The intermolecular proton exchange between 3,6-di-tert-butyl-2-hydroxphenoxyl and 3,6-di-tert-butylpyrocatechol in the presence of triethylamine was detected and investigated.
-
2.
From the specific broadenings in the ESR spectra we obtained the kinetic parameters of exchange and the thermodynamic parameters of the association of 3,6-di-tert-butylpyrocatechol with triethylamine.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
A. I. Prokof'ev, N. N. Bubnov, S. P. Solodovnikov, I. S. Belostotskaya, V. V. Ershov, and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim., 2467 (1974).
A. I. Prokof'ev, N. N. Bubnov, S. P. Solodovnikov, and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim., 2213 (1974).
A. Kerrington and E. MacLachlan, Magnetic Resonance and Its Use in Chemistry [Russian translation], Mir (1970).
R. Kreilick and S. Weissman, J. Amer. Chem. Soc.,84, 306 (1962).
D. P. Eyman and R. S. Drago, J. Amer. Chem. Soc.,88, 1617 (1966).
M. D. Joesten and R. S. Drago, J. Amer. Chem. Soc.,84, 3817 (1962).
M. Schwartz, Anionic Polymerization [Russian translation], Mir (1970).
I. S. Belostotskaya, N. L. Komissarova, É. V. Dzhuaryan, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 1594 (1972).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 306–310, February, 1975.
The initial compounds were provided by V. V. Ershov and I. S. Belostotskaya to whom the authors would like to express their gratitude.
Rights and permissions
About this article
Cite this article
Prokof'ev, A.I., Bubnov, N.N., Solodovnikov, S.P. et al. Proton exchange between 3,6-di-tert-butyl-2-hydroxyphenoxyl and 3,6-di-tert-butylpyrocatechol in the presence of triethylamine. Russ Chem Bull 24, 243–246 (1975). https://doi.org/10.1007/BF00925762
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00925762