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The reaction of vanadium(v) with hydroxyethylethylenediamine triacetic acid

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Complex formation in a solution of vanadium(V) with hydroxyethylethylenediaminetriacetic acid has been studied spectrophotometrically, and the composition and instability constant of the complex have been determined.

  2. 2.

    The rate of oxidation of hydroxyethylethylenediaminetriacetic acid in vanadium(V) solutions is first order with respect to concentrations of vanadium(V) and the acid. The order with respect to hydrogen ion is variable and fractional, the activation energy being 20.4±0.2 kcal/mole.

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Literature cited

  1. L. I. Martynenko, Nauchnye Doklady Vysshei Shkoly (Khimiya), 718 (1958).

  2. A. K. Babko, Physicochemical Analysis of Complex Compounds in Solutions [in Russian], Naukova Dumka (1955).

  3. J. E. Powell and J. Mackey, Inorg. Chem.,1, 418 (1962).

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  4. R. P. Tishchenko, N. I. Pechurova, and V. I. Spitsyn, Izv. Akad. Nauk SSSR, Ser. Khim., 2396 (1972).

  5. R. P. Tishchenko, N. I. Pechurova, L. I. Martynenko, and V. I. Spitsyn, Izv. Akad. Nauk SSSR, Ser. Khim., 1212 (1973).

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    N. I. Pechurova, R. P. Tishchenko & V. I. Spitsyn

Authors
  1. N. I. Pechurova
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  2. R. P. Tishchenko
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  3. V. I. Spitsyn
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 7–10, January, 1976.

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Pechurova, N.I., Tishchenko, R.P. & Spitsyn, V.I. The reaction of vanadium(v) with hydroxyethylethylenediamine triacetic acid. Russ Chem Bull 25, 1–3 (1976). https://doi.org/10.1007/BF00925606

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  • DOI: https://doi.org/10.1007/BF00925606

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