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Stability Constants of the Binary Vanadium(III) Complexes with the Aminopolycarboxylic Acids: Nitrilodiaceticpropionic, Nitriloaceticdipropionic, and Nitrilotripopionic Acids Studied by Potentiometric Measurements

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Abstract

We present the results of studies on the stability constants of Vanadium(III) complexes with the aminopolycarboxylic acids: nitrilodiaceticpropionic (NDAP, H3L), nitriloaceticdipropionic (NADP, H3L), and nitrilotripopionic (NTP, H3L) by potentiometric measurements in 3.0 mol·dm−3 KCl ionic medium at 25 °C. The data analysis performed with the LETAGROP computational program indicates the formation of mononuclear complexes of type: VH3L3+, VH2L2+, VHL+, VL, V(OH)L−, V(OH)2L2−, and VL 3−2 . The observed order of stability is NDAP > NADP > NTP, due to the changes induced by the acetic propionic group decreasing the stability of the formed complexes. The generated species distribution diagrams are briefly discussed.

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Acknowledgements

We thank Universidad Central de Venezuela (UCV) for all the support to complete this research work.

Funding

The authors are grateful for financing provided by the Universidad Central de Venezuela (UCV).

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Authors and Affiliations

  1. Laboratorio de Equilibrios en Solución, Departamento de Química, Universidad Simón Bolívar (USB), Apartado 89000, Caracas, 1080 A, Venezuela

    Vito Lubes, Giuseppe Lubes & Lino Hernández

  2. Centro de Equilibrios en Solución, Escuela de Química. Facultad de Ciencias, Universidad Central de Venezuela, Caracas, Venezuela

    Mary Lorena Araujo

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  1. Vito Lubes
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Contributions

GL: Conceptualization, Formal analysis, and Investigation. MLA: Conceptualization, Supervision, and Writing—review & editing. LH: Methodology, Formal analysis, Investigation, Validation, and Writing—review & editing. VL: Conceptualization, Supervision, Project administration, Formal analysis, Software, and Writing—original draft.

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Correspondence to Vito Lubes.

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The authors of this article dedicate it to the memory of Professor Dr. Felipe Brito (1930–2017), considered the father of solution chemistry in Venezuela, for all his contributions in the development of Chemistry over more than 50 years of scientific academic career in the country.

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Lubes, V., Araujo, M.L., Lubes, G. et al. Stability Constants of the Binary Vanadium(III) Complexes with the Aminopolycarboxylic Acids: Nitrilodiaceticpropionic, Nitriloaceticdipropionic, and Nitrilotripopionic Acids Studied by Potentiometric Measurements. J Solution Chem 52, 720–730 (2023). https://doi.org/10.1007/s10953-023-01261-8

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