Conclusions
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1.
Transformations in PC13-α,α,ω)-trihydroperfluoroalkanol systems have a steplike, equilibrium character.
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2.
The stability of ester acid chlorides of phosphorous acid is sharply reduced in proportion to the introduction ofα,α,ω)-trihydroperfluoroalkoxy groups to the phosphorus atom, which attests to the similar increase in its v-acceptor properties.
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Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 159–163, January, 1979.
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Fokin, A.V., Kolomiets, A.F., Komarov, V.A. et al. Reaction of α,α,ω-trihydroperfluoroalkanols with phosphorus trichloride. Russ Chem Bull 28, 148–152 (1979). https://doi.org/10.1007/BF00925413
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DOI: https://doi.org/10.1007/BF00925413