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Organoboron compounds. 350. A mass-spectrometric study of the acylamidinates and acylaminopyridinates of boron

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The fragmentation of the dialkylborylacylamidinates and dialkylborylacylaminopyridinates is similar to the fragmentation of the dialkylborylimidoylamidinates which we studied earlier, differing from the latter in breakdown of the boron-containing ring.

  2. 2.

    Fragmentation with breakdown of the boron-containing ring proceeds more extensively in the dialkylboryl[2-(α-hydroxyalkyl)aminopyridinates] than in the dialkylboryl(2-acylaminopyridinate)s, compounds with delocalized π-electron systems.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    B. M. Zolotarev, V. A. Dorokhov, O. S. Chizhov, L. I. Lavrinovich & B. M. Mikhailov

Authors
  1. B. M. Zolotarev
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  2. V. A. Dorokhov
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  3. O. S. Chizhov
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  4. L. I. Lavrinovich
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  5. B. M. Mikhailov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 80–84, January, 1979.

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Zolotarev, B.M., Dorokhov, V.A., Chizhov, O.S. et al. Organoboron compounds. 350. A mass-spectrometric study of the acylamidinates and acylaminopyridinates of boron. Russ Chem Bull 28, 70–74 (1979). https://doi.org/10.1007/BF00925400

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  • DOI: https://doi.org/10.1007/BF00925400

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