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Isomerization of 1-cyano-1-trimethylsiloxy-2-propene and its reactions with amines

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Cyanosilylated acrolein and 2-ethoxyacrolein isomerize in the presence of secondary amines and react with an excess of the latter to form derivatives of propionamide and N-substituted aminosilanes.

  2. 2.

    Unlike 1-cyano-1-trimethylsiloxy-2-ethoxy-2-propene, 1-cyano-1-trimethylsiloxy-2-propene is thermally stable and does not isomerize under the action of the Speier catalyst, colloidal nickel, ZnI2, or pyridine.

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Literature cited

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    M. G. Voronkov, N. A. Keiko, T. A. Kuznetsova, V. V. Keiko, E. O. Tsetlina & V. A. Pestunovich

Authors
  1. M. G. Voronkov
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  2. N. A. Keiko
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  3. T. A. Kuznetsova
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  4. V. V. Keiko
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  5. E. O. Tsetlina
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  6. V. A. Pestunovich
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Additional information

Translated fromIzvestiyaAkademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 906–909, April, 1978.

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Voronkov, M.G., Keiko, N.A., Kuznetsova, T.A. et al. Isomerization of 1-cyano-1-trimethylsiloxy-2-propene and its reactions with amines. Russ Chem Bull 27, 783–786 (1978). https://doi.org/10.1007/BF00925307

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  • DOI: https://doi.org/10.1007/BF00925307

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