Conclusions
The 1,3-anionic rearrangement of aryloxysilanes is an intramolecular process that does not depend on the nature of the migrating organosilyl group but is controlled by the reactivities of the labile halogen of the aryloxysilane and of the organolithium compound in the halogen-lithium exchange reaction, which generates the silyloxyarenide ion.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 890–893, April, 1978.
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Muslin, D.V., Lyapina, N.S., Kut'in, A.P. et al. Reactions of haloaryloxysilanes with organolithium compounds. Russ Chem Bull 27, 770–773 (1978). https://doi.org/10.1007/BF00925304
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DOI: https://doi.org/10.1007/BF00925304