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NMR analysis of the stereoisomers of methylvinylphenylcyclotrisiloxanes and cyclotetrasiloxanes

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Certain methylphenylvinylcyclosiloxanes have been synthesized.

  2. 2.

    Study of the PMR spectra of mixtures of the stereoisomers of the organocyclosiloxanes shows that steric interaction is of little significance in the ground state and in the reactive transition states of these compounds.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    K. A. Andrianov, B. D. Lavrukhin, V. M. Kotov, T. A. Pryakhina & T. V. Strelkova

Authors
  1. K. A. Andrianov
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  2. B. D. Lavrukhin
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  3. V. M. Kotov
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  4. T. A. Pryakhina
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  5. T. V. Strelkova
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Additional information

Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 843–850, April, 1978.

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Andrianov, K.A., Lavrukhin, B.D., Kotov, V.M. et al. NMR analysis of the stereoisomers of methylvinylphenylcyclotrisiloxanes and cyclotetrasiloxanes. Russ Chem Bull 27, 728–733 (1978). https://doi.org/10.1007/BF00925294

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  • DOI: https://doi.org/10.1007/BF00925294

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