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Geometrical structures of phosphoruscontaining heterocyclic compounds 19. Polarity and polarizability anisotropy of the phosphorus bonds in 2-hydro-2-oxo-1,3,2-dioxaphosphorinanes

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Polarization and polarizability parameters have been determined for phosphoryl bonds in axial and equatorial positions.

  2. 2.

    Components of the polarizability ellipsoid for the P-H bond have been calculated.

  3. 3.

    2-Hydro-2-oxo-5,5-dimethyl-1,3,2-dioxaphosphorinane exists as an equilibrium mixture of conformers, 80–90% equatorial and 20–10% axial.

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Literature cited

  1. B. A. Arbuzov, S. G. Vul'fson, and R. P. Arshinova, Phosphorus,4, 221 (1974).

    Google Scholar 

  2. M. Mikolajczyk and H. M. Schiebel, Angew. Chem.,81, 94 (1969).

    Google Scholar 

  3. É. E. Nifant'ev, I. S. Nasonovskii, and A. A. Borisenko, Zh. Obshch. Khim.,41, 2368 (1971).

    Google Scholar 

  4. É. E. Nifant'ev, A. A. Borisenko, I. S. Nasonovskii, and E. I. Matrosov, Dokl. Akad. Nauk SSSR,196, 121 (1971).

    Google Scholar 

  5. C. L. Bodkin and P. Simpson, J. Chem. Soc., Perkin Trans. 2, 676 (1973).

    Google Scholar 

  6. B. A. Arbuzov, R. P. Arshinova, and V. M. Zoroastrova, Dokl. Akad. Nauk SSSR,199, 1061 (1971).

    Google Scholar 

  7. T. L. Brown, J. G. Verkade, and T. S. Piper, J. Phys. Chem.,65, 2051 (1961).

    Google Scholar 

  8. H. J. Geise, Rec. Trav. Chim.,88, 362 (1967).

    Google Scholar 

  9. R. P. Arshinova and R. H. Gubaidullin, Izv. Akad. Nauk SSSR, Ser. Khim., 1076 (1977).

  10. J. G. Verkade, Thesis of the Fifth International Conference on Organic Phosphorus Chemistry, Gdansk (1974).

  11. M. J. Aroney, R. J. W. Le Fevre, and J. D. Saxby, J. Chem. Soc., 4938 (1963).

  12. B. A. Arbuzov, R. P. Arshinova, Yu. M. Mareev, I. Kh. Shakirov, and V. S. Vinogradova, Izv. Akad. Nauk SSSR, Ser. Khim., 665 (1974).

  13. H. Tolkmith, Ann. N. Y. Acad. Sci.,79, 187(1959).

    Google Scholar 

  14. E. I. Matrosov, A. A. Kryuchkov, and E. E. Nifant'ev, Izv. Akad. Nauk SSSR, Ser. Khim., 2587 (1975).

  15. A. Zwierzak, Can. J. Chem.,45, 2501 (1967).

    Google Scholar 

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Authors and Affiliations

  1. A. M. Butlerov Chemical Institute, V. I. Ul'yanov-Lenin Kazan State University, USSR

    R. P. Arshinova, V. E. Kataev & B. A. Arbuzov

  2. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    R. P. Arshinova, V. E. Kataev & B. A. Arbuzov

Authors
  1. R. P. Arshinova
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  2. V. E. Kataev
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  3. B. A. Arbuzov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 835–838, April, 1978.

The authors would like to thank V. M. Zoroastrova for having synthesized the trans isomer (II), and R. N. Gubaidullina for having obtained the chromatograms.

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Arshinova, R.P., Kataev, V.E. & Arbuzov, B.A. Geometrical structures of phosphoruscontaining heterocyclic compounds 19. Polarity and polarizability anisotropy of the phosphorus bonds in 2-hydro-2-oxo-1,3,2-dioxaphosphorinanes. Russ Chem Bull 27, 720–723 (1978). https://doi.org/10.1007/BF00925292

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  • DOI: https://doi.org/10.1007/BF00925292

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