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The production of episulfonium complexes from propylene and the regioselectivity of their reactions with nucleophiles

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The regioselectivity of the reactions of stable S-arylsulfonium complexes prepared from propylene and various nucleophiles corresponds to Markovnikov addition and the degree of selectivity of this reaction depends on the nature of the aromatic substituent. The episulfonium complexes prepared were characterized by13C NMR spectra.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. S. Gybin, M. Z. Krimer, V. A. Smit, V. S. Bogdanov & É. A. Vorob'eva

Authors
  1. A. S. Gybin
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  2. M. Z. Krimer
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  3. V. A. Smit
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  4. V. S. Bogdanov
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  5. É. A. Vorob'eva
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 563–572, March, 1979.

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Gybin, A.S., Krimer, M.Z., Smit, V.A. et al. The production of episulfonium complexes from propylene and the regioselectivity of their reactions with nucleophiles. Russ Chem Bull 28, 518–526 (1979). https://doi.org/10.1007/BF00924824

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  • DOI: https://doi.org/10.1007/BF00924824

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