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Mass-spectrometric study of compounds from the cyclopropane series 7. The behavior of the cyclopropyl thioethers under electron impact and in chemical ionization

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study has been made of certain aspects of the behavior of the cyclopropyl thioethers under electron impact (EI) and chemical ionization.

  2. 2.

    The presence of the cyclopropane ring (CPR) gives rise to strong [M-alkene]+ ion peaks in the EI spectra of the aliphatic cyclopropyl ethers and [M-CH3]+, [M-C2H5]+, and [M-SH]+ ion peaks in the EI spectra of their aromatics analogs.

  3. 3.

    The [M + H]+ ions of the aromatic cyclopropyl thioethers eliminate an ArH molecule.

  4. 4.

    The presence of two Cl atoms in the CPR reduces the stability of the M+ and [M + H]+ ions, and largely determines their further fragmentation.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. I. Kadentsev, A. Ya. Podel'ko, O. S. Chizhov, S. M. Shostakovskii & N. S. Nikol'skii

Authors
  1. V. I. Kadentsev
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  2. A. Ya. Podel'ko
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  3. O. S. Chizhov
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  4. S. M. Shostakovskii
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  5. N. S. Nikol'skii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 532–540, March, 1979.

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Kadentsev, V.I., Podel'ko, A.Y., Chizhov, O.S. et al. Mass-spectrometric study of compounds from the cyclopropane series 7. The behavior of the cyclopropyl thioethers under electron impact and in chemical ionization. Russ Chem Bull 28, 491–497 (1979). https://doi.org/10.1007/BF00924819

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  • DOI: https://doi.org/10.1007/BF00924819

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