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The oxidation of amines by molecular oxygen. 9. The liquid-phase oxidation of dimethylaniline

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The liquid-phase oxidation of dimethylaniline (DMA) proceeds through a radical-chain mechanism with second-power chain rupture. Rate constants for chain propagation and rupture have been determined.

  2. 2.

    The DMA peroxide radicals (RO .2 ) differ from the corresponding radicals of β-CH and NH bonded amines insofar as they cannot reduce inhibitors. The latter can only oxidize the DMA RO .2 .

  3. 3.

    Rate constants have been determined for the interaction of the DMA RO .2 radicals with various aromatic amines and phenols at 40°C.

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Literature cited

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Authors and Affiliations

  1. Branch of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    G. Sh. Bakhturidze, A. L. Aleksandrov & I. L. Édilashvili

  2. Institute of Physical and Organic Chemistry, Academy of Sciences of the Georgian SSR, Tbilisi

    G. Sh. Bakhturidze, A. L. Aleksandrov & I. L. Édilashvili

Authors
  1. G. Sh. Bakhturidze
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  2. A. L. Aleksandrov
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  3. I. L. Édilashvili
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 515–519, March, 1979.

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Bakhturidze, G.S., Aleksandrov, A.L. & Édilashvili, I.L. The oxidation of amines by molecular oxygen. 9. The liquid-phase oxidation of dimethylaniline. Russ Chem Bull 28, 473–478 (1979). https://doi.org/10.1007/BF00924815

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  • DOI: https://doi.org/10.1007/BF00924815

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