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Sterospecific reaction of the conjugated acylation of arylacetylenes

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The acylation of arylacetylenes by cationoid reagents in the presence of aromatic hydrocarbons proceeds as a reaction of stereospecific trans-addition, and leads to a high yield ofβ, β-diarylvinyl ketones with a strictly fixed configuration of the aromatic groups.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    S. A. Khurshudyan, A. A. Shchegolev, V. A. Smit, V. A. Chertkov & V. F. Kucherov

Authors
  1. S. A. Khurshudyan
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  2. A. A. Shchegolev
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  3. V. A. Smit
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  4. V. A. Chertkov
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  5. V. F. Kucherov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2754–2759, December, 1977.

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Khurshudyan, S.A., Shchegolev, A.A., Smit, V.A. et al. Sterospecific reaction of the conjugated acylation of arylacetylenes. Russ Chem Bull 26, 2546–2551 (1977). https://doi.org/10.1007/BF00924562

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  • DOI: https://doi.org/10.1007/BF00924562

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