Skip to main content
SpringerLink
Log in

ESR spectra of micellar aqueous solutions of the dodecyl sulfates of 2,2,6,6-tetramethyl-4-ammoniumpiperidin-1-oxyl and Mn2+

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Analysis of the ESR spectra of micelle solutions have shown the upper limit of the counterion lifetime in such solutions to be something in excess of 10−8 sec.

  2. 2.

    The degree of micelle dissociation rises markedly as the concentration of surfaceactive compound in the solution is increased. The maximum degree of dissociation is observed at the critical concentration for micelle formation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. S. Waggoner, O. H. Griffith, and C. R. Christiansen, Proc. Nat. Acad. Sci. USA,57, 1198 (1967).

    Google Scholar 

  2. A. S. Waggoner, A. D. Weith, and O. H. Griffith, J. Phys. Chem.,72, 4129 (1967).

    Google Scholar 

  3. S. Ohnishi, T. J. R. Cyr, and A. Fukushima, Bull. Chem. Soc. Jpn.,13, 673 (1970).

    Google Scholar 

  4. J. Oakes, Nature,231, 39 (1971).

    Google Scholar 

  5. K. R. Fox, Trans. Faraday Soc.,67, 2802 (1971).

    Google Scholar 

  6. G. P. Rabold, J. Polym. Sci., A1,7, 1187 (1969).

    Google Scholar 

  7. E. E. Zaev, Kolloidn. Zh.,34, 304 (1972).

    Google Scholar 

  8. E. E. Zaev and Yu. G. Grechishnikov, Kolloidn. Zh.,37, 165 (1975).

    Google Scholar 

  9. S. Miyamoto, Bull. Chem. Soc. Jpn.,33, 371 (1960).

    Google Scholar 

  10. E. G. Rozantsev, Free Nitroxyl Radicals, Plenum Press, New York-London (1970).

    Google Scholar 

  11. K. Shinoda, et al., Colloidal Surfactants: Same Physicochemical Properties, Academic Press (1963).

  12. J. Oakes, J. Chem. Soc., Faraday Trans,1, 69, 1321 (1973).

    Google Scholar 

  13. N. M. Bazhin and K. M. Salikhov, Relaxation of Free Radicals in Liquids [in Russian], Izd. Novosibirsk. Univ (1973).

  14. E. E. Zaev and L. V. Spirikhin, Izv. Sib. Otd., Akad. Nauk SSSR, Ser. Khim.,1973, No. 12, 5, 32.

  15. V. A. Ponomareva and E. E. Zaev, Zh. Prikl. Spektrosk.,21, 844 (1974).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch of the Academy of Sciences of the USSR, Ufa

    E. E. Zaev, Yu. G. Grechishnikov & L. V. Spirikhin

Authors
  1. E. E. Zaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. G. Grechishnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. V. Spirikhin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2730–2733, December, 1977.

The authors wish to thank E. G. Rozantsev for having furnished the stable radical, and R. M. Davydov, K. I. Zamaraev and Ya. S. Lebedev for useful discussions of this work.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zaev, E.E., Grechishnikov, Y.G. & Spirikhin, L.V. ESR spectra of micellar aqueous solutions of the dodecyl sulfates of 2,2,6,6-tetramethyl-4-ammoniumpiperidin-1-oxyl and Mn2+ . Russ Chem Bull 26, 2523–2526 (1977). https://doi.org/10.1007/BF00924557

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00924557

Keywords

Search

Navigation