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Reaction of anions of original salts with products of hydrolytic polymerization of Al(III) aquo ions

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    During polymerization of aquo ions of Al(III), nitrate and chloride ions take part in the formation of sol particles, forming two types of bond, strong and weak. The weakly held anions are in a state of rapid exchange with free anions of the solution.

  2. 2.

    The ClO4 − anion does not interact with the polymerization products of the aquo ions of aluminum.

  3. 3.

    The SO4 2− anion prevents the formation of hydroxo complex Al13O4 (OH)24 (H2O)12 7+ and promotes the formation of sol particles.

  4. 4.

    The broadening of the NMR lines of quadrupole nuclei in the anions and solvent is a sensitive indicator of the formation of sol particles in the solutions.

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Authors and Affiliations

  1. Institute of Catalysis, Siberian Branch of the Academy of Sciences of the USSR, Novosibirsk

    M. A. Fedotov, O. P. Krivoruchko & R. A. Buyanov

Authors
  1. M. A. Fedotov
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  2. O. P. Krivoruchko
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  3. R. A. Buyanov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2647–2651, December, 1977.

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Fedotov, M.A., Krivoruchko, O.P. & Buyanov, R.A. Reaction of anions of original salts with products of hydrolytic polymerization of Al(III) aquo ions. Russ Chem Bull 26, 2447–2450 (1977). https://doi.org/10.1007/BF00924541

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  • DOI: https://doi.org/10.1007/BF00924541

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