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Reaction of anions of original salts with products of hydrolytic polymerization of Al(III) aquo ions

  • M. A. Fedotov
  • O. P. Krivoruchko
  • R. A. Buyanov
Inorganic Chemistry
  • 23 Downloads

Conclusions

  1. 1.

    During polymerization of aquo ions of Al(III), nitrate and chloride ions take part in the formation of sol particles, forming two types of bond, strong and weak. The weakly held anions are in a state of rapid exchange with free anions of the solution.

     
  2. 2.

    The ClO4 anion does not interact with the polymerization products of the aquo ions of aluminum.

     
  3. 3.

    The SO42− anion prevents the formation of hydroxo complex Al13O4 (OH)24 (H2O)127+ and promotes the formation of sol particles.

     
  4. 4.

    The broadening of the NMR lines of quadrupole nuclei in the anions and solvent is a sensitive indicator of the formation of sol particles in the solutions.

     

Keywords

Polymerization Aluminum Chloride Nitrate SO42 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    E. Calvet, P. Boivient, M. Noel, A. Maillard, and R. Tertian, Bull. Soc. Chim. France,1953, 99.Google Scholar
  2. 2.
    B. Ilmelik, M. V. Mathieu, M. Prettre, and S. Teicher, J. Chim. Phys. Phys-Chim. Biol.,51, 651 (1954).Google Scholar
  3. 3.
    P. H. Hsu and T. F. Bates, Mineral. Mag.,33, 749 (1964).Google Scholar
  4. 4.
    G. P. Vishnyakova, V. A. Dzis'ko, L. M. Kefeli, L. F. Lokotko, I. P. Olen'kova, L. M. Plyasova, I. A. Ryzhak, and A. S. Tikhova, Kinet. Katal.,11, 1545 (1970).Google Scholar
  5. 5.
    V. A. Dzis'ko, A. S. Ivanova, and G. P. Vishnyakova, Kinet. Katal.,17, 483 (1976).Google Scholar
  6. 6.
    H. D. Bale and P. W. Schmidt, J. Chem. Phys.,31, 1612 (1959).Google Scholar
  7. 7.
    M. C. Gastuche and A. Herbillon, Bull. Soc. Chim. France,1962, 1404.Google Scholar
  8. 8.
    O. P. Krivoruchko, R. A. Buyanov, B. P. Zolotovskii, and A. A. Ostan'kovich, Izv. Akad. Nauk SSSR, Ser. Khim.,1974, 1460.Google Scholar
  9. 9.
    M. A. Fedotov, O. P. Krivoruchko, R. A. Buyanov, and B. P. Zolotovskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 1705.Google Scholar
  10. 10.
    K. F. Jahr and A. Brechlin, Z. Anorg. und Allg. Chem.,270, 257 (1952).Google Scholar
  11. 11.
    J. K. Ruff and S. Y. Tyree, J. Am. Chem. Soc.,80, 1523 (1958).Google Scholar
  12. 12.
    W. V. Rausch and H. D. Bale, J. Chem. Phys.,40, 3391 (1964).Google Scholar
  13. 13.
    J. Aveston, J. Chem. Soc.,1965, 4438.Google Scholar
  14. 14.
    J. W. Akitt, N. N. Greenwood, B. L. Khandelwall, and G. D. Lester, J. Chem. Soc. Dalton, Trans.,1972, 604.Google Scholar
  15. 15.
    J. W. Akitt, Annu. Rep. NMR Spectros. (ed. by E. F. Mooney), Academic Press, London-New York,5a, 484 (1972).Google Scholar

Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • M. A. Fedotov
    • 1
  • O. P. Krivoruchko
    • 1
  • R. A. Buyanov
    • 1
  1. 1.Institute of CatalysisSiberian Branch of the Academy of Sciences of the USSRNovosibirsk

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