Abstract
The kinetics of the direct interaction of oxide and aluminum nitride at temperatures of 1700 and 1780°C at a low pressure of p ≤ 1 Pa was studied. It was shown that the reaction without weight loss gives a two-phase nonequilibrium product ALON + AlN with the composition of ALON enriched with aluminum oxide. The reaction occurring under reducing conditions is accompanied by weight loss and gives an equilibrium two-phase product ALON + AlN, in which oxynitride spinel is enriched with aluminum nitride. The main methodological requirements for the direct synthesis of ALON with high optical and mechanical characteristics were determined.
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This work was supported under a state assignment on basic scientific research for the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia.
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Smorchkov, K.G., Gribchenkova, N.A. & Alikhanyan, A.S. Kinetic and Methodological Problems of Direct Synthesis of ALON 9Al2O3 · 5AlN. Russ. J. Inorg. Chem. 65, 668–673 (2020). https://doi.org/10.1134/S0036023620050228
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DOI: https://doi.org/10.1134/S0036023620050228