Conclusions
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1.
We have synthesized and characterized complexes of trialkylboranes with diaryl ketimines and alkyl aryl ketimines.
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2.
We have used11B NMR spectroscopy to show that complexes of tri-n-butylborane with diaryl ketimines are less stable than those with alkyl aryl ketimines. The latter in turn are more stable than coordination compounds of tri-n-butylborane with secondary amines.
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Literature cited
Progress in Boron Chemistry, Vol. 1, Pergamon Press (1964), p. 83.
B. M. Mikhailov, Boron Hydride Chemistry [in Russian], Nauka (1967).
E. L. Muetterties, The Chemistry of Boron and Its Compounds, Wiley, New York (1967), p. 443.
E. N. Gur'yanova, I. P. Gol'dshtein, and I. P. Romm, The Donor-Acceptor Bond [in Russian], Khimiya (1973).
B. M. Mikhailov, T. K. Baryshnikova, V. S. Bogdanov, and V. G. Kiselev, Zh. Obshch. Khim.,41, 1533 (1971).
B. M. Mikhailov, V. A. Dorokhov, and V. I. Seredenko, Dokl. Akad. Nauk SSSR.,199, 1328 (1971).
V. A. Dorokhov, V. I. Seredenko, and B. M. Mikhailov, Zh. Obshch. Khim.,46, 1057 (1976).
L. S. Povarov, V. N. Grigos, and B. M. Mikhailov, Izv. Akad. Nauk SSSR, Ser. Khim., 2039 (1963).
B. Samuel, R. Snaith, C. Summerford, and K. Wade, J. Chem. Soc. A, 2019 (1970).
C. Summerford and K. Wade, J. Chem. Soc. A, 2010 (1970).
I. Pattison and K. Wade, J. Chem. Soc. A, 1098 (1967).
Steric Effects in Organic Chemistry [Russian translation], IL (1960), p. 459.
J. Hinze, M. A. Whitehead, and H. H. Jaffe, J. Am. Chem. Soc.,85, 148 (1963).
K. Wade and B. K. Wyatt, J. Chem. Soc., A, 1339 (1967).
J. R. Jennings, I. Pattison, K. Wade, and B. K. Wyatt, J. Chem. Soc. A, 1608 (1967).
G. S. Eaton and W. N. Lipscomb, NMR Studies of Boron Hydrides and Related Compounds, Benjamin, New York (1969).
B. M. Maikhailov, T. K. Baryshnikova, and V. S. Bogdanov, Zh. Obshch. Khim.,43, 1949 (1973).
L. S. Vasil'ev, M. M. Vartanyan, V. S. Bogdanov, V. G. Kiselev, and B. M. Mikhailov, Zh. Obshch. Khim.,42, 1540 (1972).
V. S. Bogdanov, V. G. Kiselev, A. D. Naumov, L. S. Vasil'ev, V. P. Dmitrikov, V. A. Dorokhov, and B. M. Mikhailov, Zh. Obshch. Khim.,42, 1547 (1972).
B. M. Mikhailov, G. S. Ter-Sarkisyan, and N. N. Govorov, Izv. Akad. Nauk SSSR, Ser. Khim., 2053 (1976).
B. M. Mikhailov, V. A. Vaver, and Yu. N. Bubnov, Dokl. Akad. Nauk SSSR,126, 575 (1959).
C. Monreu and G. Mignonac, Compt. Rend. Acad. Sci.,156, 1801 (1913).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2076–2081, September, 1977.
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Mikhailov, B.M., Ter-Sarkisyan, G.S. & Govorov, N.N. Organoboron compounds 334. Complexes of trialkylboranes with ketimines. Russ Chem Bull 26, 1921–1925 (1977). https://doi.org/10.1007/BF00924390
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DOI: https://doi.org/10.1007/BF00924390