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A kinetic isotope study of the mechanism of C5-dehydrocyclization of paraffin hydrocarbons on aluminoplatinum catalysts

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Kinetic isotope methods have been used to study the catalytic reactions of 2-methylpentane on bifunctional aluminoplatinum catalysts, working over the temperature interval from 330 to 400°C.

  2. 2.

    C5-dehydrocyclization of alkanes proceeds along two different reactions paths on these catalysts, by direct cyclization to the cyclane and through intermediate olefin formation.

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Authors and Affiliations

  1. N. D. Zelenskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    O. V. Bragin, V. G. Tovmasyan, G. V. Isagulyants, A. A. Greish, L. I. Kovalenko & A. L. Liberman

Authors
  1. O. V. Bragin
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  2. V. G. Tovmasyan
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  3. G. V. Isagulyants
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  4. A. A. Greish
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  5. L. I. Kovalenko
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  6. A. L. Liberman
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2041–2044, September, 1977.

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Bragin, O.V., Tovmasyan, V.G., Isagulyants, G.V. et al. A kinetic isotope study of the mechanism of C5-dehydrocyclization of paraffin hydrocarbons on aluminoplatinum catalysts. Russ Chem Bull 26, 1886–1889 (1977). https://doi.org/10.1007/BF00924382

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  • DOI: https://doi.org/10.1007/BF00924382

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