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Decomposition of complexes of decaborane(12) with nitrogenous bases

3. Gas emission kinetics and IR spectra of hydrazinediamminedecaborane(12)

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Decomposition of hydrazinediamminedecaborane(12) leads to the evolution of hydrazine; knetically, this process is diffusion-limited.

  2. 2.

    The authors have analyzed the IR absorption spectrum of hydrazinediamminedecaborane(12), and suggest that the hydrazine molecule in hydrazinediamminedecaborane(12) is linked to the boron-nitrogen-hydrogen fragment by weak bonds — possibly hydrogen bonds.

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Authors and Affiliations

  1. Department of Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    A. S. Rozenberg & L. T. Romanova

Authors
  1. A. S. Rozenberg
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  2. L. T. Romanova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 525–528, March, 1978.

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Rozenberg, A.S., Romanova, L.T. Decomposition of complexes of decaborane(12) with nitrogenous bases. Russ Chem Bull 27, 452–455 (1978). https://doi.org/10.1007/BF00923913

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  • DOI: https://doi.org/10.1007/BF00923913

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