Conclusions
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1.
It was established that the hydrogen in sym-octahydrothioxanthene has a high hydride mobility, and the position of the compound in the series of hydride-ion donors was determined.
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2.
The previously proposed mechanism for the disproportionation of thiopyran systems, based on intermolecular hydride-ion transfer, was confirmed.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1831–1834, August, 1974.
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Blinokhvatov, A.F., Parnes, Z.N., Kharchenko, V.G. et al. Hydride mobility of the hydrogen of sym-octahydrothioxanthene. Russ Chem Bull 23, 1749–1752 (1974). https://doi.org/10.1007/BF00923203
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DOI: https://doi.org/10.1007/BF00923203