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Anisotropy of the polarizability and intramolecular interaction in para-substituted dimethylanilines

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The parameters of the ellipsoids of polarizability of the conjugated fragments N-C6H4-El in the molecules of para-substituted dimethylanilines were determined.

  2. 2.

    The introduction of donor substituents into the para-position with respect to the dimethylamino group increases the pyramidal character of the nitrogen and the noncoplanarity of the remaining fragments of the molecule.

  3. 3.

    In aromatic systems of the type studied there is a redistribution of the axes of the ellipsoids of polarizability, which is determined by the electronic nature of the substituents opposite one another.

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Authors and Affiliations

  1. V. I. Ul'yanov-Lenin Kazan' State University, USSR

    G. Ya. Cheryukanova, S. G. Vul'fson, G. A. Chmutova & A. N. Vereshchagin

  2. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Branch, Academy of Sciences of the USSR, USSR

    G. Ya. Cheryukanova, S. G. Vul'fson, G. A. Chmutova & A. N. Vereshchagin

Authors
  1. G. Ya. Cheryukanova
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  2. S. G. Vul'fson
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  3. G. A. Chmutova
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  4. A. N. Vereshchagin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1800–1804, August, 1974.

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Cheryukanova, G.Y., Vul'fson, S.G., Chmutova, G.A. et al. Anisotropy of the polarizability and intramolecular interaction in para-substituted dimethylanilines. Russ Chem Bull 23, 1720–1723 (1974). https://doi.org/10.1007/BF00923196

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  • DOI: https://doi.org/10.1007/BF00923196

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