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Kinetics of the thermal decomposition of bis(nitroalkyl)-N-nitrosoamines

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The kinetics of the thermal decomposition of bis-(2,2-dinitropropyl)-N-nitrosoamine, bis-(2,2-dinitro-2-fluoroethyl)-N-nitrosoamine, and bis-(2,2,2-trinitroethyl)-N-nitrosoamine was studied.

  2. 2.

    The reactions are described by a first-order equation. The activation energies and preexponential factors were determined.

  3. 3.

    The reaction center in the bis-(2,2,2-trinitroethyl)-N-nitrosoamine molecule is the trinitromethyl group, while in the other two compounds it is the nitrosoamine group. The mechanism of the decomposition is discussed.

  4. 4.

    The enthalpy of formation of the (NO2)2CCH2N(NO)CH2C(NO2)3 radical was calculated.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    B. L. Korsunskii, L. Ya. Kiseleva, R. G. Gafurov, E. M. Sogomonyan, L. T. Eremenko & F. I. Dubovitskii

Authors
  1. B. L. Korsunskii
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  2. L. Ya. Kiseleva
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  3. R. G. Gafurov
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  4. E. M. Sogomonyan
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  5. L. T. Eremenko
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  6. F. I. Dubovitskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1781–1786, August, 1974.

The authors would like to express sincere gratitude to V. I. Pepekin for his discussion of the results obtained.

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Korsunskii, B.L., Kiseleva, L.Y., Gafurov, R.G. et al. Kinetics of the thermal decomposition of bis(nitroalkyl)-N-nitrosoamines. Russ Chem Bull 23, 1702–1706 (1974). https://doi.org/10.1007/BF00923192

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  • DOI: https://doi.org/10.1007/BF00923192

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