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Kinetics of the hydrolysis of silicon -containing vinyl ethers

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The kinetics of the hydrolysis of (triorganylsilylalkyl)vinyl ethers with the general formula R3Si(CH2)nOCH=CH2 (n=2, 3) was studied.

  2. 2.

    The reactivity of the vinyloxy group depends on the nature of the substituents at the silicon atom and the mutual arrangement of the heteroatoms in the molecule.

  3. 3.

    One of the factors influencing the reactivity of the vinyl ethers studied is theβ-conjugation of the heteroatoms in the molecule.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    N. N. Vlasova, I. I. Tsykhanskaya & I. S. Emel'yanov

Authors
  1. N. N. Vlasova
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  2. I. I. Tsykhanskaya
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  3. I. S. Emel'yanov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1775–1778, August, 1974.

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Vlasova, N.N., Tsykhanskaya, I.I. & Emel'yanov, I.S. Kinetics of the hydrolysis of silicon -containing vinyl ethers. Russ Chem Bull 23, 1695–1698 (1974). https://doi.org/10.1007/BF00923190

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  • DOI: https://doi.org/10.1007/BF00923190

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