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Mass spectrometric study of N-oxides of quinolysidine alkaloids of the matrine series

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The mass spectra of N-oxides of matrine, allomatrine, sophoridine, isosophoridine, sophocarpine, and isosophoramine were studied.

  2. 2.

    The ions [M-17]+ are formed, at least partially, from molecular ions in one step by elimination of the OH radical.

  3. 3.

    With the aid of the peaks of the metastable ions and a comparison with the mass spectra of unoxidized alkaloids, the origin of individual ions in the spectra of the N-oxides studied was determined.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    V. G. Zaikin, Z. S. Ziyavidinova & N. S. Vul'fson

  2. M. M. Shemyakin Institute of Chemistry of Natural Compounds, Academy of Sciences of the USSR, Moscow

    V. G. Zaikin, Z. S. Ziyavidinova & N. S. Vul'fson

Authors
  1. V. G. Zaikin
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  2. Z. S. Ziyavidinova
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  3. N. S. Vul'fson
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1734–1739, August, 1974.

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Zaikin, V.G., Ziyavidinova, Z.S. & Vul'fson, N.S. Mass spectrometric study of N-oxides of quinolysidine alkaloids of the matrine series. Russ Chem Bull 23, 1657–1661 (1974). https://doi.org/10.1007/BF00923183

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  • DOI: https://doi.org/10.1007/BF00923183

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